Ordinary water, preferably distilled water is a very poor electrolyte. It contains a very low concentration H⁺ and OH^- ions and a large number of undisociated water molecules. Organic salts like C₁₀H₁₄ N₂Na₂O₈.2H₂O, C₁₀H₁₄ N₂Na₂O₈.2H₂O, behave as an intermediate between strong and weak electrolytes i.e. the current conduction is less than strong electrolytes but more than weak electrolytes. If they are electrolyzed using metal electrodes like copper, aluminium, iron e.t.c. colored solutions are obtained at first. When electrolyzed for a considerable amount of time (it depends on the amount of water, concentration of the salt e.t.c.) precipitates are formed which resemble metal hydroxides in appearance. But their distinction from metal hydroxides can be easily seen by reacting the precipitate with Ba(OH)₂.8H₂O (the solution must be heated). Ordinary metal hydroxides do not react while the said product turns white. It is mainly due to complex formation. In this paper we deal with electrolysis of C₁₀H₁₄ N₂Na₂O₈.2H₂O, C₁₀H₁₄ N₂Na₂O₈.2H₂O, ( C₆H₅)₂NH (though it is very slightly soluble in H₂O), using Cu, Fe, Sn, Al, electrodes and their interaction with heat and NO₃^- ion from a strong electrolyte (e.g. Ca(NO₃)₂.2H₂O).